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Researchers at Wageningen University in the Netherlands have reported that radiation from WiFi networks is harmful to trees. Problems observed included growth variations, and bleeding and fissures in tree bark. The researchers exposed 20 ash trees to various sources of radiation for three months. The tress closest to the WiFi source exhibited a lead-like shine on the leaves. The researchers also found that WiFi radiation is harmful to growing corn.
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If you’re thinking of buying a phone case with ‘radiation blocking material’ believing it will reduce radiation, you should know this: Phones have automatic power control, such cases act as shields  and make the phone work harder, transmitting more power, increasing heat and reducing battery life, The incoming signal to the phone will also be reduced so your phone may not work in areas of poor signal.

SAR stands for specific absorption rate, a measure of the amount of radio frequency energy absorbed by the body when using a mobile phone. The SAR rating of your cell phone can be found in your instruction manual or possibly online at this Federal Communications Commission website. In the United States, the SAR cannot exceed 1.6 watts per kilogram.

DefenderShield Cellphone Radiation Case also claims independent testing and says in their website: That a "sophisticated layering of separate non-toxic, human safe materials processed for maximum radiation blocking efficiency. Each material has unique and targeted radiation-shielding characteristics designed to work in unison to eliminate all radiation emissions from 0 to 10 GHZ and Defender Shield technology refracts, conducts and finally absorbs all these potentially harmful emissions."  In this demonstration, the radiation level measured when DefendeShield case was on is still quite a bit above the level of exposure that I would recommend. I personally do not recommend-holding a phone with a shielding case to your head as the DefenderShield website shows a young woman doing as she demonstrates the product. 
In September 2014, Californian oncologists reported four similar case histories of young women who had developed breast cancer in precisely the areas where they normally carried their smartphones. What shocked the doctors was that these women were aged 21 to 39 and had no family history or other risk factors relating to cancer. All their cancers “had striking similarity, all tumours were hormone positive… (with) an extensive intraductal component and… near-identical morphology.” (CaseRepMed., 2013).
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